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The recent theory-driven discovery of a class of clathrate hydrides (e.g., CaH₆, YH₆, YH₉, and LaH₁₀) with superconducting critical temperatures (T_c) well above 200 K has opened the prospects for “hot” superconductivity above room temperature under pressure. Recent efforts focus on the search for superconductors among ternary hydrides that accommodate more diverse material types and configurations compared to binary hydrides. Through extensive computational searches, we report the prediction of a unique class of thermodynamically stable clathrate hydrides structures consisting of two previously unreported H₂₄and H₃₀hydrogen clathrate cages at megabar pressures. Among these phases, LaSc₂H₂₄shows potential hot superconductivity at the thermodynamically stable pressure range of 167 to 300 GPa, with calculatedT_cs up to 331 K at 250 GPa and 316 K at 167 GPa when the important effects of anharmonicity are included. The very high critical temperatures are attributed to an unusually large hydrogen-derived density of states at the Fermi level arising from the newly reported peculiar H₃₀as well as H₂₄cages in the structure. Our predicted introduction of Sc in the La–H system is expected to facilitate future design and realization of hot superconductors in ternary clathrate superhydrides.